Comparative study of the effects of anatase and rutile titanium …

The anatase and rutile titanium dioxide (TiO 2) were prepared and characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscope and UV–vis spectrophotometer.Then they were introduced into waterborne polyurethane (WPU) to prepare hybrid films. The effects of anatase and rutile TiO 2 on …

Sintered high titanium agglomerates

Sintered high titanium agglomerates . United States Patent 6149712 ... A preferred titanium dioxide containing source is a deposit which includes any of the minerals rutile, anatase and leucoxene. The titanium-containing minerals may be subjected to initial concentration processing after extraction. Initial concentration processing may increase ...

Rutile | Structure, Properties, Uses | Britannica

rutile, the most abundant of three naturally occurring forms of titanium dioxide (TiO 2; see also anatase; brookite). It forms red to reddish brown, hard, brilliant metallic, slender crystals, often completely surrounded by …

Synthesis of rutile titania powders: Agglomeration, …

Rutile titania powders were synthesized via a sol-gel/hydrothermal process using nitric acid as the catalyst. A molar acid to alkoxide ratio of 10 and a water to alkoxide molar ratio of …

Role of Surface Area, Primary Particle Size, and Crystal Phase …

Several types of titania nanoparticles were used in this study. TiO 2 (P25) nanoparticle with a primary particle size of 27 nm, specific surface area of 57.4 m 2 /g, and the phase composition of 80% anatase and 20% rutile was purchased from Degussa Chemicals (Hanau, Germany). Anatase TiO 2 nanoparticles of 6, 16, 26, 38, 53, and 104 …

Rutile: The titanium mineral in white paint and star ruby

Rutile is a titanium oxide mineral with a chemical composition of TiO 2. It is found in igneous, metamorphic and sedimentary rocks throughout the world. Rutile also occurs …

R-902+ Titanium Dioxide

R-902+ Titanium Dioxide Grade Snapshot Product Description Ti-Pure™ R-902+ is a rutile titanium dioxide pigment, manufactured by the chloride process and is delivered as a fine, dry powder. Ti-Pure™ R-902+ is a product that can ... and inorganic treatments to decrease agglomerates formation and reduce total dispersion time. It is optimized

Synthesis of nanoscale high purity rutile titania by a rapid …

The production of high purity rutile titanium dioxide (TiO 2) nanoparticles was carried out by a rapid gas-phase chemical reaction under initial chemical reaction conditions (initial temperature, ignition energy and gas pressure about 100–200 °C, 40 J and 1–4 MPa, respectively). The results showed the sphere, high purity and disperse …

Morphological and Physicochemical Characterization of Agglomerates …

Titanium dioxide nanoparticles (TiO 2 NP) are possible carcinogenic materials (2B-IARC) and their toxicity depends on shape, size, and electrical charge of primary NP and on the system formed by NP media. The aim of this work was to characterize agglomerates of three TiO 2 NP by evaluating their morphometry, stability, …

Exposure Data

Chemical composition: Natural rutile, anatase and brookite contain impurities of up to ≈2% that include iron, chromium, vanadium, aluminium, niobium, tantal, hafnium and zirconium (Heaney & Banfield, 1993) and account for slight variations in density, colour and indices of refraction.Since most commercial titanium dioxide is manufactured from natural …

A novel approach for preparation of highly crystalline anatase …

In the second method of preparation, using TiCl 4 as the starting material, the XRD examination of the dry calcinated powder (TiO 2 –B1), collected at pH 3, indicated that the nanopowder was obtained as a mixture of anatase and rutile (Fig. 2 a).This result was in accordance with the finding claimed in the literature that in the intermediate Ti …

Titanium Dioxide Dispersion Monitoring for Pigment Applications

A particle size of around 0.25 microns yields the highest scattering efficiency across the entire visible spectrum for rutile titanium dioxide. For anatase titanium dioxide, the ideal particle size is around 0.3 microns. Milling to below this size significantly reduces the pigment scattering power and increases the Manufacturer's costs, both ...

Synthesis of rutile titania powders: Agglomeration, …

In this study, an investigation into industry-scalable methods for synthesizing rutile TiO2 nanorods with controllable morphological characteristics was carried out.

Synthesis and utilization of titanium dioxide nano particle …

There are various sources for titanium dioxide which is found in the form of ilmenite (40–80% TiO 2) and mineral sand deposits such as anatase (> 95%TiO 2), rutile (~ 95% TiO 2) and leucoxene ...

Mechanically Activated Rutile and Ilmenite as the …

Mechanically activated rutile ore can be used for aluminothermic reduction to produce a titanium master alloy. KClO 4 can be used, as well as CaO 2 as booster. In this regard, a remarkable amount …

Mechanically Activated Rutile and Ilmenite as the …

The consumptive conventional process of titanium alloys production needs new innovative processes. As starting materials for aluminothermic reduction, natural TiO2 and FeTiO3 concentrates can be …

Optimized dispersion of nanoparticles for biological in vitro …

The formation of coarse TiO2 (rutile) agglomerates in PBS or RPMI was prevented by addition of 1.5 mg/ml of human, bovine or mouse serum albumin, or mouse serum. The required concentration of albumin to stabilize the nanoparticle dispersion depended on the concentration of the nanoparticles in the dispersion. ... Titanium(IV) …

Mechanism, Thermodynamics and Kinetics of Rutile …

decrease in its content therein. In the reaction mi xture, at 200 °C, agglomerates are formed and cannot be leached. These agglomerates are presumably the products of the polymerization of hydrolysis forms of titanium. The formation of agglomerates inso luble in 5% sulfuric acid was observed in a few works [18,19].

Mechanically Activated Rutile and Ilmenite as the …

Mechanical activation followed by pressure leaching facilitates the leaching of ilmenite and the separation of titanium/iron by means of the synchronous hydrolysis of anatase. At 95% TiO2, the produced …

Photoactivity of Anatase–Rutile TiO 2

DOI: 10.1557/OPL.2011.1132 Corpus ID: 101740703; Photoactivity of Anatase–Rutile TiO 2 Nanocrystalline Mixtures Obtained by Heat Treatment of Titanium Peroxide Gel @article{Bakardjieva2011PhotoactivityOA, title={Photoactivity of Anatase–Rutile TiO 2 Nanocrystalline Mixtures Obtained by Heat Treatment of Titanium Peroxide Gel}, …

Low-temperature synthesis and characterization of …

When acid is added, hydroxylated titanium agglomerates are electrostatically charged, breaking into small particles, and after some time the solution becomes clear; this phenomenon is called petization [41]. At low temperature, because of the low crystallization rate, rutile, which is the most stable polymorph of TiO 2, is produced.

Rutile and titanium particles differentially affect the …

Both types of particles aggregated in the culture media and were efficiently internalized by osteoblasts as agglomerates. Treatment of isolated cultures of …

Mechanism, Thermodynamics and Kinetics of Rutile …

Rutile decomposition by sulfuric acid, including the formation of two salts, Ti(SO4)2/TiOSO4, is thermodynamically modelled. It is shown that TiO2 can spontaneously dissolve in H2SO4 solutions. However, titania is considered as an inert (ballast) phase component of titanium-containing raw materials due to the decelerated separate nature …

Rutile and its applications in earth sciences

Rutile is the most common naturally occurring titanium dioxide polymorph and is widely distributed as an accessory mineral in metamorphic rocks ranging from …

Toxic impacts of rutile titanium dioxide in Mytilus galloprovincialis

Rutile is the most common natural form of TiO 2, and it is usually used in optical elements, because it has the highest refractive index at visible wavelengths of any known crystal. ... leading to precipitation of the largest agglomerates. 4.1. Titanium concentrations in mussels' tissues.

Separating brookite and rutile from zircon and obtaining titanium …

In case a completely formed fine anatase is not required as the end product, we have found that by mixing the titanium oxide mineral zircon concentrate with about 5 to 25 parts calcined petroleum coke per 100 parts of this concentrate, and then heating the charge at such a temperaturesay 10000 C., and for such a period of time for say three ...

Influence of calcination temperature on anatase to rutile …

Titanium dioxide (TiO 2) nanoparticles with different ratios of anatase to rutile transformation were synthesized by the modified sol–gel method.The optical properties were investigated by UV–vis diffuse reflectance spectrophotometry. Phase transformation, crystallinity, and crystal structure of the calcined TiO 2 samples were …

Electron-Microscopic Investigation of the Distribution of Titanium …

The anatase NP and anatase/rutile mixture NP induced a higher CD83 and CD86 expression and a higher IL-12p40 production in vitro than the rutile NP (including coated rutile NP and a rutile NP of a ...

Brookite vs. rutile vs. anatase: What`s behind their various

The results of investigating the morphological, optical and electronic properties of three synthesized TiO 2 polymorphs (anatase (A and A2), brookite (B and …

Annealing Control on the Anatase/Rutile Ratio of …

According to the different phases at which titanium dioxide (TiO2) crystallizes, previous studies have shown that anatase is more efficient for photocatalysis than rutile. Nowadays, the synergetic effect is well …